Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Small hypervelocity particles captured in aerogel collectors: Location,extraction, handling and storage     

Andrew J. Westphal  Christopher Snead  Janet Borg  Eric Quirico  Pierre‐Ivan Raynal  Michael E. Zolensky  Gianluca Ferrini  Luigi Colangeli  Pasquale Palumbo 《Meteoritics & planetary science》2002,37(6):855-865

Abstract— It has now been about a decade since the first demonstrations that hypervelocity particles could be captured, partially intact, in aerogel collectors. But the initial promise of a bonanza of partially‐intact extraterrestrial particles, collected in space, has yet to materialize. One of the difficulties that investigators have encountered is that the location, extraction, handling and analysis of very small (10 μm and less) grains, which constitute the vast majority of the captured particles, is challenging and burdensome. Furthermore, current extraction techniques tend to be destructive over large areas of the collectors. Here we describe our efforts to alleviate some of these difficulties. We have learned how to rapidly and efficiently locate captured particles in aerogel collectors, using an automated microscopic scanning system originally developed for experimental nuclear astrophysics. We have learned how to precisely excavate small access tunnels and trenches using an automated micromanipulator and glass microneedles as tools. These excavations are only destructive to the collector in a very small area—this feature may be particularly important for excavations in the precious Stardust collectors. Using actuatable silicon microtweezers, we have learned how to extract and store “naked” particles—essentially free of aerogel—as small as 3 μm in size. We have also developed a technique for extracting particles, along with their terminal tracks, still embedded in small cubical aerogel blocks. We have developed a novel method for storing very small particles in etched nuclear tracks. We have applied these techniques to the extraction and storage of grains captured in aerogel collectors (Particle Impact Experiment, Orbital Debris Collector Experiment, Comet‐99) in low Earth orbit.  相似文献   

SN 1999E: another piece in the supernova–gamma-ray burst connection puzzle     

L. Rigon  M. Turatto  S. Benetti  A. Pastorello  E. Cappellaro  I. Aretxaga  O. Vega  V. Chavushyan  F. Patat  I. J. Danziger  M. Salvo 《Monthly notices of the Royal Astronomical Society》2003,340(1):191-196

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Solid solutions in mineral nomenclature     

E. H. Nickel 《Mineralogy and Petrology》1992,46(1):49-53

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The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献   

Pulsar Wind Nebulae in Egret Error Boxes     

Mallory S. E. Roberts  Crystal L. Brogan  Bryan M. Gaensler  Jason W. T. Hessels  C.-Y. Ng  Roger W. Romani 《Astrophysics and Space Science》2005,297(1-4):93-100

A remarkable number of pulsar wind nebulae (PWN) are coincident with EGRET γ-ray sources. X-ray and radio imaging studies of unidentified EGRET sources have resulted in the discovery of at least six new pulsar wind nebulae (PWN). Stationary PWN (SPWN) appear to be associated with steady EGRET sources with hard spectra, typical for γ-ray pulsars. Their toroidal morphologies can help determine the geometry of the pulsar which is useful for constraining models of pulsed γ-ray emission. Rapidly moving PWN (RPWN) with more cometary morphologies seem to be associated with variable EGRET sources in regions where the ambient medium is dense compared to what is typical for the ISM.  相似文献   

Five WC9 stars discovered in the AAO/UKST Hα survey     

E. C. Hopewell  M. J. Barlow  J. E. Drew  Y. C. Unruh  Q. A. Parker  M. J. Pierce  P. A. Crowther  C. Knigge  S. Phillipps  A. A. Zijlstra 《Monthly notices of the Royal Astronomical Society》2005,363(3):857-866

We report the discovery of five massive Wolf–Rayet (WR) stars resulting from a programme of follow-up spectroscopy of candidate emission-line stars in the Anglo-Australian Observatory United Kingdom Schmidt Telescope (AAO/UKST) Southern Galactic Plane Hα survey. The 6195–6775 Å spectra of the stars are presented and discussed. A WC9 class is assigned to all five stars through comparison of their spectra with those of known late-type WC stars, bringing the known total number of Galactic WC9 stars to 44. Whilst three of the five WC9 stars exhibit near-infrared (NIR) excesses characteristic of hot dust emission (as seen in the great majority of known WC9 stars), we find that two of the stars show no discernible evidence of such excesses. This increases the number of known WC9 stars without NIR excesses to seven. Reddenings and distances for all five stars are estimated.  相似文献   

Controlled Direction Reception Filtering of P- and S-Waves In τ-P Space     

S. A. Greenhalgh  I. M. Mason  E. Lucas  D. Pant  R. T. Eames 《Geophysical Journal International》1990,100(2):221-234

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Entry dynamics and acoustics/infrasonic/seismic analysis for the Neuschwanstein meteorite fall     

D. O. REVELLE  P. G. BROWN  P. SPURNÝ 《Meteoritics & planetary science》2004,39(10):1605-1626

Abstract— We have analyzed several types of data associated with the well‐documented fall of the Neuschwanstein meteorites on April 6, 2002 (a total of three meteorites have been recovered). This includes ground‐based photographic and radiometer data as well as infrasound and seismic data from this very significant bolide event (Spurný et al. 2002, 2003). We have also used these data to model the entry of Neuschwanstein, including the expected dynamics, energetics, panchromatic luminosity, and associated fragmentation effects. In addition, we have calculated the differential efficiency of acoustical waves for Neuschwanstein and used these values to compare against the efficiency calculated using available ground‐based infrasound data. This new numerical technique has allowed the source height to be determined independent of ray tracing solutions. We have also carried out theoretical ray tracing for a moving point source (not strictly a cylindrical line emission) and for an infinite speed line source. In addition, we have determined the ray turning heights as a function of the source height for both initially upward and downward propagating rays, independent of the explicit ray tracing (detailed propagation path) programs. These results all agree on the origins of the acoustic emission and explicit source heights for Neuschwanstein for the strongest infrasonic signals. Calculated source energies using more than four different independent approaches agree that Neuschwanstein was certainly <500 kg in initial mass, given the initial velocity of 20.95 km/s, resulting in an initial source energy ≤0.0157‐0.0276 kt TNT equivalent (4.185 times 10¹² J). Local source energies at the calculated infrasonic/seismic source altitudes are up to two orders of magnitude smaller than this initial source energy.  相似文献   

Numerical Modeling of the Largest Terrestrial Meteorite Craters     

B. A. Ivanov 《Solar System Research》2005,39(5):381-409

Multi-ring impact basins have been found on the surfaces of almost all planetary bodies in the Solar system with solid crusts. The details of their formation mechanism are still unclear. We present results of our numerical modeling of the formation of the largest known terrestrial impact craters. The geological and geophysical data on these structures accumulated over many decades are used to place constraints on the parameters of available numerical models with a dual purpose: (i) to choose parameters in available mechanical models for the crustal response of planetary bodies to a large impact and (ii) to use numerical modeling to refine the possible range of original diameters and the morphology of partially eroded terrestrial craters. We present numerical modeling results for the Vredefort, Sudbury, Chicxulub, and Popigai impact craters and compare these results with available geological and geophysical information.  相似文献